Amine-containing olefin copolymer with CO2-switchable oil absorption and desorption

Global decrease in crude oil resources and frequent crude oil leaks cause the energy crisis and ecological pollution. The absorption and release of leaked crude oil through absorption materials are a necessary process for environmental protection and recycling. In this article, a CO₂-responsive olefin copolymer was obtained by copolymerization of styrene and an amine-containing olefin monomer. The structure of resultant copolymer was characterized by FTIR; thermal properties and CO₂-responsive morphology changes were determined by DSC/TGA and SEM, respectively. Copolymers had certain absorption capacity for toluene with absorption rate up to 180.0%. The absorbed toluene could be released upon CO₂ stimulation with desorption rate up to 84.6%. The CO₂-responsive copolymer could be regenerated through a simple heating process and showed stable absorption–desorption performance even after being recycled for 4 times. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47439.     

酸碱理论及其在有机反应中的应用研究

酸碱反应无论是在无机化学还是有机化学中,都占有极高的地位,文章以综述的形式讨论酸碱理论及其在一些重要的有机反应中应用研究。     

离子液体水热法辅助合成稀土Ce掺杂ZnO纳米材料的制备及其应用研究

以1-甲基咪唑和氯代正丁烷为原料,合成1-丁基-3-甲基咪唑氯盐离子液体;以醋酸锌[Zn(Ac)2]、硫酸锌(ZnSO4)和氯化锌(ZnCl2)为锌源,在1-丁基-3-甲基咪唑氯盐离子液体和丙氨酸体系中与硝酸铈反应,经水热合成法制备得到Ce掺杂的纳米ZnO。采用扫描电子显微镜(SEM)、紫外-可见光吸收光谱(UV-Vis)、X射线衍射仪(XRD)、X射线光电子能谱分析(XPS)和红外光谱(FT-IR)对产品进行表征。以亚甲基蓝(MB)为目标降解物,采用UV-Vis检测,考察了Ce掺杂的纳米ZnO的光催化活性。研究表明,焙烧温度对光催化的晶体结构和光催化活性产生较大的影响;2%Ce/ZnO、焙烧温度为500℃、催化时间为30 min、亚甲基蓝用量0.05 g、pH值为10时降解率可达99.5%以上。     

基于一种改进逐点比较插补法的激光打标机控制加工算法

在激光打标系统中,逐点比较插补法是一种普遍使用的算法。这种算法在控制激光运动轨迹和对图像轨迹的拟合过程中,起到极其重要的作用。由于逐点比较插补法具有运算直观,脉冲输出均匀,调节方便等特点,所以是一种较为适合打标机系统应用的插补算法。但是传统的逐点比较插补算法存在精度低和速度慢等问题。为了改善该算法的性能,对传统逐点比较插补算法进行了改进,并进行了计算和模拟仿真。结果表明改进比较插补算法在精度和速度上都有明显提高。     

Malic acid production from renewables: a review

Malic acid derived from fossil resources is currently applied in the food and beverage industries with a medium global production capacity. However, in the transition from a fossil-based to a bio-based economy, biotechnologically produced l -malic acid may become an important platform chemical with many new applications, especially in the field of biopolymers. In this review, currently used petrochemical production routes to dl -malic acid are outlined and insights into possible bio-based alternatives for microbial l -malic acid production are provided. Besides ecological reasons, the possibility to produce enantiopure l -malic acid by microbial fermentation is the biggest advantage over chemical synthesis. State-of-the-art and open challenges concerning production host engineering, substrate choice and downstream processing are addressed. With regard to production hosts, a literature overview is given covering the leading natural production strains of Aspergillus, Ustilago and Aureobasidium, as well as Escherichia coli as the most important engineered recombinant host. The utilization of renewable substrates as an alternative to glucose is emphasized in particular as a key aspect for a competitive bio-based production. Out of the alternative substrates discussed in this review, the industrial side-streams crude glycerol and molasses seem to be most promising for large-scale l -malic acid production. © 2019 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.     

多介质立体取样及在北黄海油气化探中的应用

由于不同环境条件下,不同化探测试指标受到不同的因素干扰,所以不同介质样品的应用条件存在一定的差异。针对不同介质样品特点,分别采集海底沉积物、底部海水和低空大气3种介质样品,并采用在海底沉积物柱状样不同深度部位取样的立体取样方法,通过多指标综合分析,对不同介质和深度样品的多项化探指标互相进行了验证和补充,可以抑制干扰因素的影响,为油气资源远景评价提供依据。运用该方法在北黄海盆地油气勘查中进行初步尝试,并据此划分了三级化探异常区,提出了有利的含油气远景区,均与已知油气区和区域地质分析的结果相符合,取得了很好的效果。      

磺基琥珀酸双2-丁基辛酯钠盐的合成及表面活性测定

以马来酸酐和2-丁基辛醇为原料,经酯化得到相应的双酯,以乙醇作混相促进剂,使双酯与亚硫酸氢钠进行磺化反应,合成了磺基琥珀酸双2-丁基辛酯钠盐。采用正交试验对酯化反应条件进行了优化。合成产物的临界胶束浓度(cmc)值为3.58×10-6mol/L,表面张力(γcmc)为27.568mN/m。     

当前腐败现象的特点和对策分析

论述了当前腐败现象的表现和特点,分析了产生腐败现象的主要原因,提出了治理腐败现象的对策措施: 建立有效的教育机制、严格的用人机制、规范的决策机制、健全的管理机制、完善的监督机制和有力的责任追究机制,建立科学的法人治理结构并实行纪检监察机构派驻制。     

机载高分辨力SAR实时运动补偿的实现

本文详细地分析了载机运动误差与回波相位的关系,提出了基于G4DSP信号处理板的机载SAR实时运动补偿方法,该方法利用G4DSP的四个CPU构成流水线处理器,采用子孔径方法分段提取回波的多普勒调频斜率,然后利用调频斜率的变化计算载机的运动误差,通过相位误差函数与方位数据的时域相乘补偿运动误差。实时信号处理机的实验表明,本文方法能实时和有效的实现机载SAR运动补偿,获得满意的成像质量。